Chemo-enzymatic cascade processes are invaluable due to their ability to rapidly construct high-value products from available feedstock chemicals in a one-pot relay manner. In an article, author is Zhu, Xiaojing, once mentioned the application of 1116-77-4, Name is 4,4-Diethoxy-N,N-dimethyl-1-butanamine, molecular formula is C10H23NO2, molecular weight is 189.3, MDL number is MFCD00671479, category is ethers-buliding-blocks. Now introduce a scientific discovery about this category, Computed Properties of C10H23NO2.
First insights into the formation and long-term dynamic behaviors of nonextractable perfluorooctanesulfonate and its alternative 6:2 chlorinated polyfluorinated ether sulfonate residues in a silty clay soil
Per- and polyfluoroalkyl substances (PFAS) are persistent and toxic contaminants that are ubiquitous in the environment. They can incorporate into soil as nonextractable residues (NER) which are not detectable with conventional analytical protocols but are still possible to remobilize with changes of surrounding conditions, and thus will be bioavailable again. Therefore, there is a need to investigate thoroughly the long-term fate of NER-PFAS. In this study, a 240-day incubation of perfluorooctanesulfonate (PFOS) and its alternative 6:2 chlorinated polyfluorinated ether sulfonate (F-53B) in a silty clay topsoil was carried out. Solvent extraction, alkaline hydrolysis and sequential chemical degradation were applied on periodically sampled soil to obtain extractable, moderately bound and deeply bound PFAS, respectively. The results confirmed the formation of NER of both compounds but with different preferences of incorporating mechanisms. NER-PFOS was formed predominantly by covalent binding (via head group) and strong adsorption (via tail group). The formation of NER-F-53B was mainly driven by physical entrapment. Both bound compounds within the incubation period showed three-stage behaviors including an initial period with slight release followed by a (re) incorporating stage and a subsequent remobilizing stage. This work provides some first insights on the long-term dynamic behaviors of nonextractable PFAS and will be conducive to their risk assessment and remediation (e.g. estimating potential NER-PFAS level based on their free extractable level, and selecting remediation methods according to their prevailing binding mechanisms). (C) 2020 Elsevier B.V. All rights reserved.
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