Chemistry can be defined as the study of matter and the changes it undergoes. You¡¯ll sometimes hear it called the central science because it is the connection between physics and all the other sciences, starting with biology. 2752-17-2, Name is 2,2′-Oxydiethanamine, molecular formula is , belongs to ethers-buliding-blocks compound. In a document, author is Hsieh, Hsiang-Hua, Formula: C4H12N2O.
Synthesis, structural and DFT interpretation of titanium bis-isopropoxide derivatives incorporating bidentate ketiminate ligands
A series of titanium compounds containing bidentate ketiminate ligands are synthesized and structurally characterized. Reaction between one or two equivalents of L-DIP-H with Ti((OPr)-Pr-i)(4) in diethyl ether results the formation of titanium bis-isopropoxide compound, Ti(L-DIP)(2)((OPr)-Pr-i)(2) (1). Similarly, the combination of Ti((OPr)-Pr-i)(4) and bidentate ketiminate precursor, L-MOP-H and L-MOMP-H affords the respective compounds, Ti(L-MOP)(2)((OPr)-Pr-i)(2) (2) and Ti(L-MOMP)(2)((OPr)-Pr-i)(2) (3), respectively, in moderate yield. Additionally, we discuss the synthetic routes for the formation of 1 using different substrates, TiPh((OPr)-Pr-i)(3) or TiCl((OPr)-Pr-i)(3) with L-DIP-H or lithiated ligand LiLDIP via ligand re-distribution. We, later on, describe the concurrence of electronic disposition and steric restraint with TiO bond length and Ti-O-C bond angles.
Sometimes chemists are able to propose two or more mechanisms that are consistent with the available data. If a proposed mechanism predicts the wrong experimental rate law, however, the mechanism must be incorrect.Welcome to check out more blogs about 2752-17-2, in my other articles. Formula: C4H12N2O.