Application of 24743-14-4, The chemical industry reduces the impact on the environment during synthesis 24743-14-4, name is 3-(3-Methoxyphenyl)-1-propene, I believe this compound will play a more active role in future production and life.
Dihydroxylation of compound 36 (1.5 g, 10.1 mmol) with OsO4 followed the same method as adopted for 2 and the crude product 39 (1.73 g, 9.73 mmol, 91%) was used for the next step. mp 90-92 C. 1H NMR (400 MHz, CDCl3, delta): 7.22 (t, J = 7.7 Hz, 1H), 6.79 (m, 3H), 3.93 (m, 1H), 3.79 (s, 3H), 3.67 (m, 1H), 3.50 (m, 1H), 2.73 (m, 2H), 2.32 (m, 2H). 13C NMR (100.6 MHz, CDCl3, delta): 159.8, 139.3, 129.7, 121.6, 115.6, 115.1, 111.9, 72.9, 66.1, 55.2, 39.9. IR (neat): 3391, 2939, 2836, 1602, 1585, 1489, 1455, 1437, 1259, 1153, 1092, 1038, 781, 697 cm-1. EIMS (70 eV) m/z: 182.0 (M+, 27.6), 151.0 (21.2), 122.0 (100), 121.0 (44.8), 107.0 (24.7), 91.0 (11.8), 77.0 (20.7). HRMS-EI (m/z): M+ calcd for C10H14O3, 182.0943; found 182.0948.
In the field of chemistry, the synthetic routes of compounds are constantly being developed and updated. I will also mention this compound in other articles, 3-(3-Methoxyphenyl)-1-propene, other downstream synthetic routes, hurry up and to see.
Reference:
Article; Tripathi, Subhankar; Chan, Ming-Huan; Chen, Chinpiao; Bioorganic and Medicinal Chemistry Letters; vol. 22; 1; (2012); p. 216 – 221;,
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem